2022: Direct numerical simulation of gas-liquid mass transfer around a spherical contaminated bubble in the stagnant-cap regime

Abstract Direct Numerical Simulations are performed to investigate the gas-liquid mass transfer around a rising spherical bubble contaminated by insoluble surfactants. The surfactant transport on the bubble surface and the Marangoni effect are taken into account when solving the hydrodynamics, resulting in the stagnant-cap condition. A parametric study is carried out to investigate the mass transfer by varying the Reynolds, […]

2022: Luminescent probe synthesis for oxygen visualization technique: Application to the effect of surfactant structure on oxygen mass transfer

Abstract Planar Laser Induced Fluorescence with Inhibition (PLIF-I) is a powerful technique for studying the local gas/liquid oxygen mass transfer from a single rising bubble. However, to track oxygen in the liquid phase, it is necessary to use an oxygen sensitive luminescent probe, which needs to be unreactive toward the liquid phase. This article presents […]

2022: Effect of surfactant lengths on gas-liquid oxygen mass transfer from a single rising bubble

Abstract This work is an experimental investigation of the effect of the nature of surfactants on oxygen mass transfer. The study focuses on three cationic surfactants with different hydrophobic chain lengths, and four nonionic surfactants with different hydrophilic chain lengths. Equilibrium adsorption isotherms are calculated for each surfactant from experimental values of surface tension in […]

2022: Gas-liquid mass transfer characterization in a thin shrinking film at an atomization nozzle

Abstract In this paper, a light absorption method is applied to estimate the thickness of an atomizing liquid film at microscale that exits a spraying nozzle. By using a dioxygen sensitive dye, called resazurin, it is also possible to determine the local profile of dioxygen concentration resulting from the gas-liquid transfer from air into the liquid film. […]

2022: Taylor bubble formation and flowing in a straight millimetric channel with a cross-junction inlet geometry.

Part I: Bubble dynamics Abstract The investigations of bubble formation dynamics at a cross-junction in a straight milli-channel were reported. The bubble formation process could be divided into the filling and squeezing stages, and their frequencies were compared at various conditions. It was found that the filling and squeezing frequencies were controlled mainly by the […]

2022: Effect of surfactant lengths on gas-liquid oxygen mass transfer from a single rising bubble

Abstract This work is an experimental investigation of the effect of the nature of surfactants on oxygen mass transfer. The study focuses on three cationic surfactants with different hydrophobic chain lengths, and four nonionic surfactants with different hydrophilic chain lengths. Equilibrium adsorption isotherms are calculated for each surfactant from experimental values of surface tension in […]

2021: Gas–Liquid Mass Transfer around a Rising Bubble: Combined Effect of Rheology and Surfactant (open access)

The influence of viscosity and surface tension on oxygen transfer was investigated using planar laser-induced fluorescence with inhibition (PLIF-I). The surface tension and the viscosity were modified using Triton X-100 and polyacrylamide, respectively. Changes in the hydrodynamic parameters of millimetric bubbles were identified, and transfer parameters were calculated. The results revealed a decrease in the […]

2020: Sudden Decrease of the Dissolved Ozone Concentration in Sprays: A Mass Transfer Phenomenon?

Ozone is known to be a powerful oxidant with low persistence and has been shown to possess biocidal activity against a wide number of fungi and bacteria. These properties make ozone a good candidate as a substitute for chemical phytosanitary products in agriculture. However, when water containing dissolved ozone is sprayed, the concentration of ozone […]

2020: Gas-liquid mass transfer around Taylor bubbles flowing in a long, in-plane, spiral-shaped milli-reactor

Abstract Gas–liquid mass transfer was investigated around Taylor bubbles flowing in a long, in-plane, spiral-shaped milli-reactor involving various configurations. Using a colorimetric technique and image post-treatment, the variation of the equivalent O2 concentration inside the liquid slugs was measured. The coloration positions, corresponding to 99% of the maximum concentration reached in the liquid slug, changed significantly […]

2020: Comparison of three different techniques for gas-liquid mass transfer visualization

Abstract In this article three different techniques for visualizing gas-liquid mass transfer are reviewed according to their applications in air-water systems. The three techniques are: Planar Laser Induced Fluorescence (PLIF with the use of fluorescent resorufin), PLIF with Inhibition (PLIF-I with the use of a ruthenium complex), and a colorimetric technique (using a redox reaction […]